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Install software:

opkg update
opkg install python-openssl

nano /mnt/sda1/gmail.py

#!/usr/bin/python
import smtplib
from email.mime.text import MIMEText
USERNAME = "[email protected]"
PASSWORD = "xxxxxx"
MAILTO  = "[email protected]"
msg = MIMEText('Hello,\nMy name is Yun, \nhow are you')
msg['Subject'] = 'Mail from Yun'
msg['From'] = USERNAME
msg['To'] = MAILTO
server = smtplib.SMTP('smtp.gmail.com:587')
server.ehlo_or_helo_if_needed()
server.starttls()
server.ehlo_or_helo_if_needed()
server.login(USERNAME,PASSWORD)
server.sendmail(USERNAME, MAILTO, msg.as_string())
server.quit()

chmod 755 /mnt/sda1/gmail.py

/mnt/sda1/gmail.py